I don’t know who made the first spacesuit, but I would suspect the scientist working for NASA at the time. The interesting thing is that it takes a wide range of scientists in designing one!
From a human biologist (bit obvious), to physicists that know what sort of forces and conditions may be in the outer space, and material scientists that know the properties of each material so that they can provide the right one that won’t tear up /break under certain conditions. And don’t forget the engineers, who will take all these pieces of information together and make the design.
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