That’s tough – I think the biggest things are galaxies which can contain billions of stars and have a massive black hole at their centre.
The biggest single things though are either massive stars which can have 100-200 times the mass of the sun. Or enormous gas clouds that form stars. (It depends on whether you think a cloud is one thing or not!)
Probably the largest “things” (depending on how you define things) in the Universe are “super-clusters” of galaxies. The Milky Way (our galaxy) belongs to a relatively small group of about 30 galaxies. Super-clusters are made up of thousands of these small (and sometimes much larger) groups. The extend over millions of light-years.
The Universe itself is quite possibly infinite so I guess the largest things within them are galaxies or galaxy-clusters; these contain billions of stars that may in turn have billions of planets orbiting them…
The biggest single things in the universe (not made up of separate bits) are supermassive black holes, which makes sense as they’re also the heaviest! The biggest know supermassive black hole is about ten billion times heavier than the sun (which means its weight in kilograms is a one with 40 zeroes after it!) and is about 1,000,000,000,000,000 times bigger! (that’s a quadrillion times bigger!). That means its surface would be 200 hundred times further out than Pluto!
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